232nd National Meeting of the American Chemical Society
The following results were presented at the 232nd National Meeting of the American Chemical Society, September 10-14, 2006 in San Francisco, CA
Dilute cellulose hydrolysis study by XRD, NMR and SEM
Haibo Zhao1, Ja Hun Kwak, kwak@pnl.gov2, J. M. White, jm.white@pnl.gov3, Yong Wang, yongwang@pnl.gov2, and Johnathan E Holladay, john.holladay@pnl.gov1. (1) Institute for Integrated Catalysis, Pacific Northwest National Lab, 902 Battelle Blvd, P.O. Box 999, MSIN: K8-93, Richland, WA 99352, (2) Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, MS K8-93, Richland, WA 99352, (3) Institute for Integrated Catalysis, Pacific Northwest National Lab and University of Texas, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352
Reverse temperature-dependent swelling pathway of trifluoroacetic acid in cellulose
Z. Conrad Zhang, conrad.zhang@pnl.gov1, Haibo Zhao1, Johnathan E Holladay, john.holladay@pnl.gov1, J. M. White, jm.white@pnl.gov2, and Yong Wang, yongwang@pnl.gov3. (1) Institute for Integrated Catalysis, Pacific Northwest National Lab, 902 Battelle Blvd, P.O. Box 999, MSIN: K8-93, Richland, WA 99352, (2) Institute for Integrated Catalysis, Pacific Northwest National Lab and University of Texas, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, (3) Institute for Integrated Catalysis, Pacific Northwest National Laboratory, MS K8-93, P. O. Box 999, Richland, WA 99352
Adsorption studies on BaO/theta-Al2O3/NiAl(100) model NOx storage materials
Janos Szanyi, janos.szanyi@pnl.gov, Institute for Integrated Catalysis, Pacific Northwest National Laboratory, M.S. K8-93, P. O. Box 999, Richland, WA 99352, Emrah Ozensoy, emrah.ozensoy@pnl.gov, Interfacial Chemistry and Engineering, Chemical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, MSIN K8-93, Richland, WA 99352, and Charles HF. Peden, chuck.peden@pnl.gov, Chemical Sciences Division, Pacific Northwest National Laboratory, M.S. K8-93, P.O. Box 999, Richland, WA 99352.
Surface reactions of alcohols on TiO2(110) investigated by in situ scanning tunneling microscopy
Zhenrong Zhang, zhenrong.zhang@pnl.gov1, A. Bondarchuk, oleksander.bondarchuk@pnl.gov1, Jooho Kim2, Bruce D. Kay, bruce.kay@pnl.gov2, J. M. White, jm.white@pnl.gov3, and Zdenek Dohnálek, zdenek.dohnalek@pnl.gov2. (1) Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, TX 78712, Richland, WA 99352, (2) Fundamental Science Directorate and and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352, (3) Institute for Integrated Catalysis, Pacific Northwest National Lab and University of Texas, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352
Solid acid catalyzed isobutane/butene alkylation in dense CO2-based media: Experiments and modeling
Sagar Sarsani, sagar@ku.edu1, Christopher Lyon, lyon@ku.edu2, Yong Wang, yongwang@pnl.gov3, and Bala Subramaniam, bsubramaniam@ku.edu1. (1) Department of Chemical & Petroleum Engineering, University of Kansas, Center for Environmentally Beneficial Catalysis, 1501 Wakarusa Drive, Lawrence, KS 66047, (2) Center for Environmentally Beneficial Catalysis, University of Kansas, 1501 Wakarusa Drive, Lawrence, KS 66047, (3) Institute for Integrated Catalysis, Pacific Northwest National Laboratory, MS K8-93, P. O. Box 999, Richland, WA 99352
Structure and reactivity of bimetallic Ni-Au catalysts for syngas production and utilization
Ya-Huei Chin, chin@berkeley.edu1, David L King, david.king@pnl.gov2, Yong Wang, yongwang@pnl.gov2, and Hyun-Seog Roh, hsroh@kier.re.kr3. (1) Department of Chemical Engineering, University of California, Berkeley, 201 Gilman Hall, Berkeley, CA 94720-1462, (2) Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99354, (3) Korea Institute of Energy Research, 71-2, Jang-dong, Yuseong-gu, Daejeon 305-343, South Korea
Surface chemistry on rutile
J. M. White, jm.white@pnl.gov1, Zhenrong Zhang, zhenrong.zhang@pnl.gov2, Oleksander A. Bondarchuk3, Zdenek Dohnalek4, Bruce Kay, bruce.kay@pnl.gov4, and MA. Henderson4. (1) Institute for Integrated Catalysis, Pacific Northwest National Lab and University of Texas, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, (2) Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, TX 78712, Richland, WA 99352, (3) Center for Materials Chemistry, University of Texas, Texas Materials Institute, Austin, TX, TX 78712, (4) Pacific Northwest National Laboratory
Growth and characterization of nanoporous oxide thin films using molecular beam techniques
Jooho Kim, Zdenek Dohnálek, zdenek.dohnalek@pnl.gov, and Bruce D. Kay, bruce.kay@pnl.gov. Fundamental Science Directorate and and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352
Investigation of the potential application of MgO in Ni-YSZ SOFC anodes
XianQin Wang, xianqin.wang@pnl.gov, Hyun-Seog Roh, David L King, david.king@pnl.gov, Ya-Huei Chin, chin@berkeley.edu, Yong Wang, yongwang@pnl.gov, and Yuanbo Lin. Institute for Integrated Catalysis, Pacific Northwest National Laboratory, MS K8-93, P. O. Box 999, Richland, WA 99352
Molecular beam studies of nanoscale films of amorphous solid water
R. Scott Smith, zorro@pnl.gov1, John L. Daschbach2, Tykhon Zubkov, tykhon.zubkov@pnl.gov1, and Bruce D. Kay, bruce.kay@pnl.gov3. (1) Pacific Northwest National Laboratory, 902 Battelle Blvd., P.O. Box 999, M/S K8-88, Richland, WA 99352, (2) Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, (3) Fundamental Science Directorateand and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352
Catalytic decomposition of sulfuric acid on silicon carbides for sulfur-based thermochemical water spliting cycles
Ja Hun Kwak, kwak@pnl.gov1, Yong Wang, yongwang@pnl.gov1, Daniel M. Ginosar, Daniel.Ginosar@inl.gov2, and Lucia M. Petkovic, Lucia.Petkovic@inl.gov2. (1) Institute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, MS K8-93, Richland, WA 99352, (2) Chemical Sciences, Idaho National Laboratory, P.O. Box 1625, MS 2208, Idaho Falls, ID 83415-2208
Structure and catalytic activity of WO3 clusters on TiO2(110)
A. Bondarchuk, oleksander.bondarchuk@pnl.gov1, Jooho Kim2, J. M. White, jmwhite@mail.utexas.edu3, Bruce Kay, bruce.kay@pnl.gov2, and Zdenek Dohnálek, zdenek.dohnalek@pnl.gov2. (1) Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, TX 78712, Richland, WA 99352, (2) Fundamental Science Directorateand and Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352, (3) Department of Chemistry, Univerisity of Texas, Austin, TX 78712
The effect of water on the adsorbed NOx species over BaO/Al2O3 NOx Storage Materials: A combined FTIR and in situ time-resolved XRD study
Charles H. F. Peden, chuck.peden@pnl.gov1, Janos Szanyi, janos.szanyi@pnl.gov1, Do Heui Kim, do.kim@pnl.gov1, Ja Hun Kwak, kwak@pnl.gov1, XianQin Wang, xianqin.wang@pnl.gov1, William S. Epling, wepling@cape.uwaterloo.ca2, and Jonathan C. Hanson3. (1) Institute for Integrated Catalysis, Pacific Northwest National Laboratory, EMSL, MS K8-93, P. O. Box 999, Richland, WA 99352, (2) Department of Chemical Engineering, University of Waterloo, DWE 2507, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada, (3) Chemistry Department, Brookhaven National Laboratory, Bldg.555, Upton, NY 11973
TiO2-based nanocomposite materials as highly active photocatalysts: The role of adlineation sites
Gonghu Li1, Le Chen1, Shannon Ciston, s-ciston@northwestern.edu2, Tijana Rajh, rajh@anl.gov3, and Kimberly A. Gray, k-gray@northwestern.edu4. (1) Department of Civil and Environmental Engineering, Northwestern University, 2145 Sheridan Rd, Rm A236, Evanston, IL 60208, (2) Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Rd., Rm A225, Evanston, IL 60208, (3) Chemistry Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, (4) Department of Civil and Environmental Engineering, Institute of Environmental Catalysis, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208