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Institute for Integrated Catalysis

CTI Publications


Weber, R.S. 2021. “Electrocatalysts for Using Renewably-Sourced, Organic Electrolytes for Redox Flow Batteries.” Catalysts 11(3), 315. doi: 10.3390/catal11030315


Akhade, S.A., N. Singh, O.Y. Gutiérrez, J. Lopez-Ruiz, H. Wang, J.D. Holladay, Y. Liu, A. Karkamkar, R.S. Weber, A.B. Padmaperuma, M. Lee, G.A. Whyatt, M. Elliott, J.E. Holladay, J.L. Male, J.A. Lercher, R. Rousseau, and V. Glezakou. 2020. "Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review." Chemical Reviews. PNNL-SA-155470. doi: 10.1021/acs.chemrev.Oc00158

Andrews E.M., J.A. Lopez-Ruiz, J.D. Egbert, K. Koh, U. Sanyal, M. Song, and D. Li, et al. 2020. "Performance of Base and Noble Metals for Electrocatalytic Hydrogenation of Bio-oil-derived Oxygenated Compounds." ACS Sustainable Chemistry & Engineering. PNNL-SA-149793. doi:10.1021/acssuschemeng.9b07041

Fernandez Rivas D., D.C. Boffito, J. Faria-Albanese, J. Glassey, J. Cantin, N. Afraz, and H. Akse, et al. 2020. "Process Intensification Education Contributes to Sustainable Development Goals. Part 2." Education for Chemical Engineers 32. PNNL-SA-152969. doi: 10.1016/j.ece.2020.05.001

Fernandez Rivas D., D.C. Boffito, J. Faria-Albanese, J. Glassey, N. Afraz, H. Akse, and K.V. Boodhoo, et al. 2020. "Process Intensification Education Contributes to Sustainable Development Goals. Part 1." Education for Chemical Engineers 32. PNNL-SA-150312. doi: 10.1016/j.ece.2020.04.003

Holladay, J.E., J.L. Male, R. Rousseau, and R.S. Weber. 2020. "Synthesizing Clean Transportation Fuels from CO2 Will at Least Quintuple the Demand for Non-Carbogenic Electricity in the U.S." Energy Fuels. PNNL-SA-155078. doi: 0.1021/acs.energyfuels.0c02595

Lopez-Ruiz, J.A., Qiu, Y., Andrews, E. et al. 2020. “Electrocatalytic valorization into H2 and hydrocarbons of an aqueous stream derived from hydrothermal liquefaction.” J Appl Electrochem. PNNL-SA-152138. doi: 10.1007/s10800-020-01452-x

Lopez-Ruiz, J.A., Y. Qiu, E. Andrews, O.Y. Gutiérrez, and J.D. Holladay. 2020. "Electrocatalytic Valorization into H2 and Hydrocarbons of an Aqueous Stream Derived from Hydrothermal Liquefaction." Journal of Applied Electrochemistry. PNNL-SA-152138. doi: 10.1007/s10800-020-01452-x

Qiu, N., J. Lopez-Ruiz, U. Sanyal, E. Andrews, O. Gutiérrez, J. Holladay. 2020. "Anodic Electrocatalytic Conversion of Carboxylic Acids on Thin Films of RuO2, IrO2, and Pt." Applied Catalysis B: Environmental, 277(15). PNNL-SA-153956. doi: 10.1016/j.apcatb.2020.119277

Sanyal, U., K. Koh, L.C. Meyer, A. Karkamkar, and O.Y. Gutiérrez. 2020. "Simultaneous Electrocatalytic Hydrogenation of Aldehydes and Phenol Over Carbon-supported Metals." Journal of Applied Electrochemistry. PNNL-SA-155530. doi: 10.1007/s10800-020-01464-7

Sanyal, U., Koh, K., Meyer, L.C. et al. 2020. “Simultaneous electrocatalytic hydrogenation of aldehydes and phenol over carbon-supported metals.” J Appl Electrochem. PNNL-SA-155530. doi: 10.1007/s10800-020-01464-7

Sanyal, U., S.F. Yuk, K. Koh, M. Lee, K. Stoerzinger, D. Zhang, L.C. Meyer, J.A. Lopez-Ruiz, A. Karkamkar, J.D. Holladay, D.M. Camaioni, M. Nguyen, V. Glezakou, R. Rousseau, O.Y. Gutiérrez, and J. Lercher. 2020. "Hydrogen Bonding Enhances the Electrochemical Hydrogenation of Benzaldehyde in the Aqueous Phase." Angewandte Chemie. PNNL-SA-155228. doi:

Singh N., U. Sanyal, G.M. Ruehl, K.A. Stoerzinger, O.Y. Gutierrez-Tinoco, D.M. Camaioni, and J.L. Fulton, et al. 2020. "Aqueous Phase Catalytic and Electrocatalytic Hydrogenation of Phenol and Benzaldehyde Over Platinum Group Metals." Journal of Catalysis 382. PNNL-SA-150490. doi:10.1016/j.jcat.2019.12.034

Yuk, S.F., M. Lee, S.A. Akhade, M. Nguyen, V. Glezakou, R.J. Rousseau. 2020. "First-principle Investigation on Catalytic Hydrogenation of Benzaldehyde Over Pt-group Metals." Catalysis Today. doi: 10.1016/j.cattod.2020.07.039


Andrews, E.M., J.D. Egbert, U. Sanyal, J.D. Holladay, and R.S. Weber. 2019. "Anode-Boosted Electrolysis in Electrochemical Upgrading of Bio-oils and in the Production of H2." Energy & Fuels. PNNL-SA-145714. doi:10.1021/acs.energyfuels.9b02524

Egbert J.D., E.C. Thomsen, S.A. O'Neill-Slawecki, D.M. Mans, L.J. Edwards, C.E. Wade, and R.S. Weber, et al. 2019. "Development and Scale-up of Continuous Electrocatalytic Hydrogenation of Functionalized Nitro arenes, Nitriles and Unsaturated Aldehydes." Organic Process Research & Development. PNNL-SA-139588. doi:10.1021/acs.oprd.8b00379

Koh K., U. Sanyal, M. Lee, G. Cheng, M. Song, V. Glezakou, and Y. Liu, et al. 2019. "Electrochemically tunable proton coupled electron transfer in Pd-catalyzed benzaldehyde hydrogenation." Angewandte Chemie International Edition. PNNL-SA-144918. doi:10.1002/ange.201912241

Lopez-Ruiz J.A., E.M. Andrews, S.A. Akhade, M. Lee, K. Koh, U. Sanyal, and S.F. Yuk, et al. 2019. "Understanding the role of metal and molecular structure on the electrocatalytic hydrogenation of oxygenated organic compounds." ACS Catalysis. PNNL-SA-145054. doi:10.1021/acscatal.9b02921

Nguyen M, SA Akhade, DC Cantu, M Lee, V Glezakou, R Rousseau. 2019. "Electro-reduction of organics on metal cathodes: A multiscale-modeling study of benzaldehyde on Au (111)." Catalysis Today. doi:10.1016/j.cattod.2019.05.067

Singh N., M. Lee, S.A. Akhade, G. Cheng, D.M. Camaioni, O.Y. Gutierrez-Tinoco, V.-A. Glezakou, R. Rousseau, J.A. Lercher, and C.T. Campbell. 2019. "Impact of pH on Aqueous-Phase Phenol Hydrogenation Catalyzed by Carbon-Supported Pt and Rh." ACS Catalysis 9:1120-1128. PNNL-SA-138664. doi:10.1021/acscatal.8b04039

Singh N., U. Sanyal, J.L. Fulton, O.Y. Gutierrez-Tinoco, J.A. Lercher, and C.T. Campbell. 2019. "Quantifying Adsorption of Organic Molecules on Platinum in Aqueous Phase by Hydrogen Site Blocking and in Situ X-ray Absorption Spectroscopy." ACS Catalysis 9, no. 8:6869-6881. PNNL-SA-144087. doi:10.1021/acscatal.9b01415

Weber, R.S. 2019. "Normalizing Hetereogeneous Electrocatalytic and Photocatalytic Rates." ACS Omega 4(2):4109-4112. PNNL-SA-140084. doi:10.1021/acsomega.8b03377

Weber, R.S., and L.J. Snowden-Swan. 2019. "The Economics of Numbering-up a Chemical Process Enterprise." Journal of Advanced Manufacturing and Processing. PNNL-SA-140580. doi:10.1002/amp2.10011

Yang, G., S. A. Akhade, X. Chen, Y. Liu, M.-S. Lee, V.-A. Glezakou, R. Rousseau, J. A. Lercher, Angew. 2019. "The Nature of Hydrogen Adsorption on Platinum in the Aqueous Phase". Angewandte Chemie International Edition 58(11):3527-3532. PNNL-SA-134839. doi:10.1002/anie.201813958


Cantu, D.C., A.B. Padmaperuma, M.-T. Nguyen, S.A. Akhade, Y. Yoon, Y.-G. Wang, M.-S. Lee, V.-A. Glezakou, R. Rousseau, and M.A. Lilga. 2018. "A Combined Experimental and Theoretical Study on the Activity and Selectivity of the Electrocatalytic Hydrogenation of Aldehydes." ACS Catalysis 8(8):7645-7658. PNNL-SA-132938. doi:10.1021/acscatal.8b00858

Du, L., Y. Shao, J. Sun, G. Yin, C. Du, and Y Wang. 2018. "Electrocatalytic Valorisation of Biomass Derived Chemicals." Catalysis Science & Technology 8(8):7645-7658. PNNL-SA-129236. doi:10.1039/C8CY00533H

Egbert J.D., J.A. Lopez-Ruiz, S. Prodinger, J.D. Holladay, D.M. Mans, C.E. Wade, and R.S. Weber. 2018. "Counting Surface RedoxSites in Carbon-supported Electrocatalyst by Cathodic Stripping of O Depositedby N2O." Journal of Catalysis 365:405-410. PNNL-SA-134666. doi:10.1016/j.jcat.2018.07.026

Lister T., L.A. Diaz, M.A. Lilga, A.B. Padmaperuma, Y. Lin, V.M. Palakkal, and C.G. Arges. 2018. "Low-Temperature Electrochemical Upgrading of Bio-oils Using Polymer Electrolyte Membranes Energy and Fuels." Energy Fuels, 32(5):5944–5950. PNNL-SA-138288. doi:10.1021/acs.energyfuels.8b00134

Lopez-Ruiz, J., U. Sanyal, J. Egbert, O. Gutiérrez, and J. Holladay. 2018. "Kinetic Investigation of the Sustainable Electrocatalytic Hydrogenation of Benzaldehyde on Pd/C. Effect of Electrolyte Composition and Half-Cell Potentials." ACS Sustainable Chemical & Engineering 6(12):16073-16085. doi:10.1021/acssuschemeng.8b02637

Mirts E.N., I.D. Petrik, P. Hosseinzadeh, M.J. Nilges, and Y. Lu. 2018. "A Designed Heme-[4Fe-4S] Metalloenzyme Catalyzes Sulfite Reduction Like the Native Enzyme." Science 361, no. 6407:1098-1101. PNNL-SA-138512. doi:10.1126/science.aat8474

Onik K., M. Gackowski, M.A. Derewinski, and B. Sulikowski. 2018. "Mesoporous Layered Aluminosilicates Prepared from Protozeolitic Nanoclusters: Synthesis, Physicochemical and Catalytic Properties." The Journal of Physical Chemistry C, 122(45):25983–25991. PNNL-SA-136327. DOI:10.1021/acs.jpcc.8b07748

Peters J.W., D.N. Beratan, B.P. Bothner, R.B. Dyer, C.S. Harwood, Z.M. Heiden, R. Hille, A.K. Jones, P.W. King, Y. Lu, C.E. Lubner, S.D. Minteer,D.W. Mulder, S. Raugei, G.J. Schut, L.C. Seefeldt, M. Tokmina-Lukaszewska, O.A.Zadvornyy, P. Zhang, and M.W.W. Adams. 2018. "A New Era for Electron Bifurcation." Current Opinion in Chemical Biology 47:32-38. PNNL-SA-138678. doi:10.1016/j.cbpa.2018.07.026

Prodinger S., A. Vjunov, J.Z. Hu, J.L. Fulton, D.M. Camaioni, M.A. Derewinski, and J.A. Lercher. 2018. "Elementary Steps of Faujasite Formation Followed by in situ Spectroscopy." Chemistry of Materials 30(3):888-897. PNNL-SA-130041. doi:10.1021/acs.chemmater.7b04554

Prodinger S., H. Shi, H. Wang, M.A. Derewinski, and J.A. Lercher. 2018. "Impact of Structural Defects and Hydronium Ion Concentration on the Stability of Zeolite BEA in Aqueous Phase." Applied Catalysis B: Environmental 237:996-1002. PNNL-SA-133584. doi:10.1016/j.apcatb.2018.06.065

Sanyal, U., J. Lopez-Ruiz, A.B. Padmaperuma, J. Holladay, and O.Y. Gutiérrez. 2018. "Electrocatalytic Hydrogenation of Oxygenated Compounds in Aqueous Phase." Organic Process Research and Development 22(12):1590–1598. PNNL-SA-137711. DOI:10.1021/acs.oprd.8b00236

Sanyal, U.,  Y. Song, N. Singh, J.L. Fulton, J. Herranz, A. Jentys, O.Y. Gutiérrez, and J.A. Lercher. 2018. "Structure Sensitivity in Hydrogenation Reactions on Pt/C in Aqueous-Phase." ChemCatChem 11, no 1. PNNL-SA-138838. doi: 10.1002/cctc.201801344

Singh N., M.-T. Nguyen, D.C. Cantu, B.L. Mehdi, N.D. Browning, J.L. Fulton, M. Balasubramanian, O.Y. Gutierrez, V.-A. Glezakou, R. Rousseau, N. Govind, D.M. Camaioni, C.T. Campbell, and J.A.Lercher. 2018. "Carbon-supported Pt during Aqueous Phenol Hydrogenation with and without Applied Electrical Potential: X-ray Absorption and Theoretical Studies of Structure and Adsorbates." Journal of Catalysis 368:8-19. PNNL-SA-136451. doi:10.1016/j.jcat.2018.09.021

Song Y., U. Sanyal, D. Pangotra, J.D. Holladay, D.M. Camaioni, O.Y. Gutierrez-Tinoco, and J.A. Lercher. 2018. "Hydrogenation of Benzaldehyde via Electrocatalysis and Thermal Catalysis on Carbon-supported Metals." Journal of Catalysis 359:68-75. PNNL-SA-125668. doi:10.1016/j.jcat.2017.12.026

Weber R.S., and J.E. Holladay. 2018. "Modularized Production of Value-Added Products and Fuels from Distributed Waste Carbon-RichFeedstocks." Engineering 4(3):330-335. PNNL-SA-135520. doi:10.1016/j.eng.2018.05.012

Weber R.S., J.E. Holladay, C. Jenks, E.A. Panisko, L.J.Snowden-Swan, M. Ramirez-Corresdores, B. Baynes, L.T. Angenent, and D. Boysen. 2018. "Modularized Production of Fuels and Other Value-Added Products from Distributed, Wasted or Stranded Feedstocks." Wiley Interdisciplinary Reviews: Energy and Environment 7(6):e308. PNNL-SA-131136.doi:10.1002/wene.308

Weber, R.S. 2018. "Effective Use of Renewable Electricity for Making Renewable Fuels and Chemicals." ACS Catalysis 9(2):946-950. PNNL-SA-139348. doi: 10.1021/acscatal.8b04143


Prodinger S., H. Shi, S. Eckstein, J.Z. Hu, M.V. Olarte, D.M. Camaioni, M.A. Derewinski, and J.A. Lercher. 2017. "Stability of Zeolites in Aqueous Phase Reactions." Chemistry of Materials 29(17):7255-7262. PNNL-SA-123271. doi:10.1021/acs.chemmater.7b01847

Prodinger S., M.A. Derewinski, Y. Wang, N.M. Washton, E.D. Walter, J. Szanyi, F. Gao, Y. Wang, and C.H.F.Peden. 2017. "Sub-micron Cu/SSZ-13: Synthesis and Application as Selective Catalytic Reduction (SCR) Catalysts." Applied Catalysis. B, Environmental 201:461-469. PNNL-SA-117975. doi:10.1016/j.apcatb.2016.08.053


Devaraj A., V. Murugesan, J. Bao, M.F. Guo, M.A. Derewinski, Z. Xu, M.J. Gray, S. Prodinger, and K.K. Ramasamy. 2016. "Discerning the Location and Nature of Coke Deposition from Surface to Bulk of Spent Zeolite Catalysts." Scientific Reports 6, Article number 37586. PNNL-SA-113562. doi:10.1038/srep37586

Gackowski M., E. Bielanska, K. Szczepanowicz, P. Warszynski, and M.A. Derewinski. 2016. "Deposition of Zeolite Nanoparticles onto Porous Silica Monolith." Surface Innovations 4(2):88-101. PNNL-SA-115505. doi:10.1680/jsuin.15.00023

Prodinger S., M.A. Derewinski, A. Vjunov, S.D. Burton, I. Arslan, and J.A. Lercher. 2016. "Improving Stability of Zeolites in Aqueous Phase via Selective Removal of Structural Defects." Journal of the American Chemical Society 138(13):4408–4415. PNNL-SA-113662. doi:10.1021/jacs.5b12785

Singh N., Y. Song, O.Y. Gutierrez, D.M. Camaioni, C.T. Campbell, and J.A. Lercher. 2016. "Electrocatalytic Hydrogenation of Phenol over Platinum and Rhodium: Unexpected Temperature Effects Resolved." ACS Catalysis 6(11):7466-7470. PNNL-SA-120400. doi:10.1021/acscatal.6b02296

Song Y., S.H. Chia, U. Sanyal, O.Y. Gutierrez, and J.A. Lercher. 2016. "Integrated Catalytic and Electrocatalytic Conversion of Substituted Phenols and Diaryl Ethers." Journal of Catalysis 344:263-272. PNNL-SA-121485. doi:10.1016/j.jcat.2016.09.030

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