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Institute for Integrated Catalysis

Scale-up of Aviation Biofuels from Alcohols Reaching New Heights

PNNL and industry partners achieve biofuel milestone, producing 5 gallons of synthetic paraffinic kerosene from CO derived alcohols

(July 2016)

PNNL and industry-partner, LanzaTech, are converting alcohols derived from captured carbon monoxide into synthetic paraffinic kerosene, a non-fossil-based jet fuel. Image credit: Scott ButnerzoomEnlarge Image.

Over the course of a 10-hour flight, a passenger airliner burns roughly 36,000 gallons of fuel—about one gallon every second. With nearly 30,000 commercial flights taking off each day in the United States, developing cleaner alternative sources of jet fuel is a priority for the airline industry and DOE’s Bioenergy Technologies Office (BETO)(Offsite link).

With funding from BETO, PNNL has been working with industry-partner, LanzaTech(Offsite link), to convert alcohols derived from captured carbon monoxide, a byproduct in the production of steel, into synthetic paraffinic kerosene, a non-fossil-based jet fuel. The technology does not only provide a viable source of sustainable jet fuel but also reduces the amount of greenhouse gasses emitted into the atmosphere.

The team recently reached a significant milestone on the project, producing over five gallons of synthetic paraffinic kerosene in a lab environment; five gallons is the quantity needed for “fit for purpose” testing. The accomplishment is part of the technology transfer process moving from bench top at PNNL to piloting at Freedom Pines, Georgia. With tight fuel specification requirements, both the demonstration of the process and the fit for purpose testing need to take place before the technology can be adopted commercially. By partnering with PNNL, LanzaTech is doing just that, transferring technology from the lab scale to industry use and preparing the quantities to gain fuel approval.

Dehydration-Oligomerization Demystified. The process works in two stages. First, LanzaTech captures waste carbon from refineries and manufacturing plants. LanzaTech feeds the CO-rich gas to microbes that consume the gas and produce ethanol. By itself, ethanol is unsuitable for jet engines because it contains oxygen and just doesn’t have the energy needed. After removing the oxygen, the resulting molecule, ethylene, is a gas and simply doesn’t have the properties to be used in today’s carefully engineered turbofan engines. Consequently, during the second stage of the process, the ethanol is run through a PNNL-developed catalyst that converts ethanol to jet fuel by removing the oxygen and combining hydrocarbons, a process known as dehydration-oligomerization.

However, ethanol dehydration-oligomerization technologies are typically difficult to control. To overcome the challenge, PNNL borrowed technology it developed to convert methanol-to-gasoline and created a new, specialized catalyst. The catalyst first removes water from the ethanol (dehydration), leaving behind ethylene. The small ethylene hydrocarbons are then combined (oligomerization) to form hydrocarbon chains large enough for jet fuel without forming aromatics that lead to sooting when burned. The fuel meets all the specifications required for use in commercial aviation—not an easy thing to do.

Producing 5 gallons of jet fuel at PNNL’s Bioproducts, Sciences, and Engineering Laboratory (BSEL)(Offsite link) demonstrated the catalyst is ready for the next stage in testing. Intermediate testing will seek to produce 2,000 gallons of jet fuel. As we successfully meet milestones, LanzaTech will scale up further ultimately providing a new way to produce the highest quality sustainable fuels for aviation.

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